p-Menthane-3,8-diol (PMD) CAS 42822-86-6 DEET-Free Repellent Ingredient
Name: p-Menthane-3,8-diol
Cas: 42822-86-6
Purity: 99%
MOQ: 1KG
Directory Guidance on p-Menthane-3,8-diol
Chemical Structure

Basic Info
| Specification Parameter | Standard Requirement | Test Standard / Method |
| CAS Registry Number | 42822-86-6 | EC No: 255-953-7 / INCI: Menthane-3,8-diol |
| Chemical Name | 2-(2-hydroxypropan-2-yl)-5-methylcyclohexan-1-ol | IUPAC Nomenclature |
| Molecular Formula / Weight | C₁₀H₂₀O₂ | 172.27 g/mol |
| Active Purity (Total Isomers) | ≥ 98.0% | Gas Chromatography (GC-FID) |
| Cis / Trans Isomer Ratio | 60:40 to 70:30 (Optimized Efficacy) | GC Peak Integration |
| Physical Appearance (25°C) | Colorless to pale yellow crystalline solid or viscous liquid | Visual Inspection |
| Odor Profile | Mild, sweet, cooling minty-eucalyptus scent | Sensory Evaluation |
| Melting Point Range | 40°C – 45°C | Capillary Melting Apparatus |
| Solubility Profile | Soluble in Ethanol, Isopropanol, Glycols; Sparingly soluble in water | Gravimetric Assessment |
Product Packaging
FAQ
A: PMD is widely recognized as the only plant-derived active ingredient with repellent protection times comparable to synthetic DEET. Unlike DEET, PMD does not melt plastics or synthetic fabrics, features a pleasant herbal mint aroma, and is generally preferred for sensitive skin and family-friendly formulations.
A: PMD should be stored in original, tightly sealed drums in a cool, dry, well-ventilated warehouse away from direct sunlight and heat sources (recommended storage temperature: 15°C to 25°C). Avoid prolonged exposure to air to prevent moisture absorption.
A: We supply PMD in 25 kg fiber drums lined with double PE bags, 50 kg plastic drums, or 200 kg steel drums for high-volume manufacturers. Each shipment includes a batch-specific Certificate of Analysis (COA), Safety Data Sheet (SDS), and technical support for custom formulation development.
Related References
Pubchem-p-Menthane-3,8-diol
Chemicalbook-p-Menthane-3,8-diol
Regulatory Compliance & Global Certifications
Navigating global biocide regulations requires rigid quality tracking. Shandong Zhishang Chemical provides comprehensive compliance support to streamline your brand’s regional registration:
ISO 9001:2015 Certification: Enforces strict quality management protocols across raw material selection, catalytic transformation, distillation, and nitrogen-sealed filling.
EPA & EU Biocidal Products Regulation (BPR) Data Support: Our PMD technical data aligns with guidelines established by major environmental protection frameworks for registered active substances.
REACH Compliance Documentation: Complete analytical dossiers available for European Union importers and downstream formulators.
Cruelty-Free & Sustainable Origin Verification: Processed without animal testing, utilizing renewable terpene feedstocks to satisfy consumer demand for clean-label insect repellents.
Because insect repulsion performance depends heavily on structural isomer distribution and low impurity thresholds, each export production lot of p-Menthane-3,8-diol undergoes four-step laboratory verification before Certificate of Analysis (COA) release:
GC-FID Isomer Quantification: Measures total purity (≥ 98.0%) and verifies the specific ratio of cis-PMD and trans-PMD to guarantee optimal vapor evaporation rates.
Residual Isopulegol & Citronellal Assay: Limits unreacted terpene precursors (Isopulegol < 0.5%, Citronellal < 0.2%) via gas chromatography to minimize potential skin sensitization risks.
Heavy Metal Trace Analysis (ICP-OES): Confirms Lead (< 5 ppm) and Arsenic (< 1 ppm) remain well below global cosmetic and personal safety limits.
Thermogravimetric Loss on Drying: Checks moisture and volatile organic solvent residues to maintain clear dissolution when diluted into alcohol-based or aqueous lotion systems.
Manufacturer of p-Menthane-3,8-diol
1. For products ≤50kg, we recommend using express delivery, which is usually called DDU service (discounted, convenient).
2. For products ≤500kg, we generally recommend air freight, which is usually called FOB, CFR or CIF service (fast and efficient).
3. For products >500kg, we generally recommend shipping by sea, which is usually called FOB, CFR or CIF service (economical, safe).
4. For high-value products, please choose air or express to ensure the safety of product transportation.






